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After initially not making the squad for the finals, he was subsequently nominated as the replacement for the injured Marco Reus. Mustafi was selected in Germany's 30-man provisional squad before the 2014 FIFA World Cup by Löw.
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Joachim Löw called up Mustafi to the German national squad for a friendly match against Chile in February 2014, he made his full international debut in a friendly match against Poland, playing the full 90 minutes of a goalless draw at the Volksparkstadion on. Mustafi celebrating Germany's victory in the 2014 FIFA World CupĮligible to represent Germany, North Macedonia and Albania, Mustafi played for his country of birth at youth level with the under-17 team he won the 2009 UEFA European Under-17 Championship. On 2 September 2021, Mustafi joined La Liga club Levante on a two-year deal. He made his debut five days later in a 0–3 defeat against RB Leipzig in the Bundesliga. He was reportedly signed as the replacement for Liverpool-bound Ozan Kabak on a six-month contract.
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On 1 February 2021, Mustafi joined German side Schalke 04 on a permanent transfer. During his tenure at Arsenal, Mustafi developed a reputation for errors. The following 1 February, Arsenal and Mustafi reached a mutual agreement to terminate his contract. On 29 August 2020, Mustafi missed Arsenal's victory over Liverpool in the 2020 FA Community Shield because of injury. He missed the 2020 FA Cup Final against the same team due to a hamstring injury, and Arsenal won 2–1. On, Mustafi was an unused substitute in the Europa League final against Chelsea, in which Arsenal were defeated by 4–1.
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He made a mistake in the 18th minute that allowed Sergio Agüero to score the first goal of a 3–0 City win. On 25 February 2018, Mustafi was in the starting 11 against Manchester City in the EFL Cup final. Because of illness, he missed Arsenal's 2–1 win over Chelsea in the 2017 FA Cup Final on 27 May. On 22 January 2017, he scored his first goal for the club in a home 2–1 league win over Burnley. Mustafi beat Bacary Sagna's record unbeaten start of 17 games at the club in Arsenal's 3–3 draw against Bournemouth with his 18th game without defeat. He made his debut in Arsenal's 2–1 Premier League win over Southampton at the Emirates Stadium on 10 September. On 30 August 2016, Mustafi joined English club Arsenal for an undisclosed fee, reported to be in excess of £35 million. He then pleaded for the team's forgiveness by the Che supporters. On 3 March 2016, Mustafi received a straight red card in the first half of Valencia's 7–0 loss at Barcelona in the first leg of the Copa del Rey semi-final, after conceding a penalty with a foul on Lionel Messi. In Valencia's next match on 2 November, against another regional rival, Villarreal, Mustafi scored a brace in a 3–1 away win to put Valencia into second place in the league. A month later, he scored his first goal for the team, opening a 3–1 home win over Elche. He debuted for his new team on 25 September, against Córdoba in an eventual 3–0 home win. On 7 August 2014, Mustafi signed a five-year deal with La Liga's Valencia CF, for an undisclosed fee, rumoured to be €8 million.
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On 26 October of the following year he scored his first professional goal, netting the game's only against Atalanta at the Stadio Luigi Ferraris. He made his debut in the Italian top flight on 11 November 2012, starting in a 0–2 loss at Palermo. It was his maiden appearance in the competition, as Sampdoria returned to Serie A at first attempt. Mustafi made his Samp debut on, starting and playing the full 90 minutes of a 1–3 loss at Varese. Mustafi was released by Everton after he asked manager David Moyes to allow him to move on for more game time.
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In January 2012, Mustafi moved to Italian Serie B side Sampdoria, on a free transfer. Mustafi only appeared on the bench nine times in the following two campaigns, but never played in any further matches. He was also named on the bench for the Premier League matches against Arsenal and Manchester City in January. Mustafi made his competitive debut on 16 December 2009, replacing Tony Hibbert in the 75th minute of a 0–1 home loss against BATE Borisov, for the season's UEFA Europa League. He later stated that " Goodison Park feels like home", after turning down offers from Manchester City and Newcastle United. In May 2009, Mustafi joined Everton, initially assigned to the Academy team.